Material Safety Data Sheet
Barium Sulfate
ACC# 02510
Section 1 - Chemical Product and Company Identification |
MSDS Name: Barium Sulfate
Catalog Numbers:
B68-500, B75-12, B75-212, B75-250LB, B75-500
Synonyms:
Artificial barite; enamel white; permanent white; sulfuric acid
barium salt.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
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CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7727-43-7 |
Barium sulfate |
>99 | 231-784-4 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: white to yellow solid.
Caution! May cause eye and skin irritation. May
cause respiratory tract irritation. May cause lung damage.
Target Organs: Lungs.
Potential Health Effects
Eye:
Dust may cause mechanical irritation.
Skin:
Dust may cause mechanical irritation.
Ingestion:
No hazard expected in normal industrial use.
Inhalation:
No hazard expected in normal industrial use.
Chronic:
Repeated exposure may cause baritosis characterized by deposition of
particulate matter in the lung.
Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Material will not burn.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 1; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Barium sulfate
|
10 mg/m3 TWA
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10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust)
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15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
|
OSHA Vacated PELs:
Barium sulfate:
10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
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Physical State: Solid
Appearance: white to yellow
Odor: odorless
pH: Not available.
Vapor Pressure: Not applicable.
Vapor Density: Not applicable.
Evaporation Rate:Negligible.
Viscosity: Not applicable.
Boiling Point: Not applicable.
Freezing/Melting Point:1580 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:4.4 (Water=1)
Molecular Formula:BaSO4
Molecular Weight:233.4
Section 10 - Stability and Reactivity
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Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Aluminum + heat.
Hazardous Decomposition Products:
Oxides of sulfur, barium fume.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
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RTECS#:
CAS# 7727-43-7:
CR0600000; CR0630000
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 7727-43-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
No information reported.
Physical:
No information available.
Other:
None.
Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
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US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
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UN Number: |
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Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7727-43-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7727-43-7: immediate.
Section 313
This material contains Barium
sulfate (listed as Barium compounds, n.o.s.), >99%, (CAS# 7727-43-7)
which is subject to the reporting requirements of Section 313 of
SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7727-43-7 can be found on the
following state right to know lists: New Jersey, (listed as Barium
compounds, n.o.s.), Pennsylvania, Minnesota, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7727-43-7: 0
Canada - DSL/NDSL
CAS# 7727-43-7 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7727-43-7 is not listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 12/12/1997
Revision #8 Date: 2/11/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.